Question detail

Describe the reaction that occurs when aqueous copper(II) ions are treated with ammonia. What is the observation and the resulting complex ion?

Try the question, check the answer, then read the explanation to understand the curriculum point.

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Reactions of ions in aqueous solution (A-level only)

Question

Describe the reaction that occurs when aqueous copper(II) ions are treated with ammonia. What is the observation and the resulting complex ion?

Answer

When aqueous copper(II) ions (Cu^2+) are treated with ammonia (NH3), a deep blue solution forms due to the formation of the complex ion [Cu(NH3)4]^2+. The observation is a color change to deep blue. This answer is anchored to Aqueous ion tests (A-level only).

Explanation

When aqueous copper(II) ions (Cu^2+) are treated with ammonia (NH3), a deep blue solution forms due to the formation of the complex ion [Cu(NH3)4]^2+. The observation is a color change to deep blue. is the best answer because it directly supports the AQA A-Level Chemistry objective to describe reactions of aqueous metal ions with ammonia. This reasoning is anchored to Aqueous ion tests (A-level only) in Reactions of ions in aqueous solution (A-level only), and it separates ammonia from similar A-Level ideas rather than relying on a vague recall statement. Other options are weaker if they use the wrong evidence, calculation, mechanism, observation, unit, or conclusion for this subtopic.

Common mistake

Misidentifying Precipitate Colors

Students often incorrectly identify the colors of precipitates formed when aqueous metal ions react with ammonia, confusing them with those formed with sodium hydroxide.

To accurately describe the reactions, remember the specific colors associated with each metal ion when reacting with ammonia. For example, copper(II) ions produce a blue precipitate of copper(II) hydroxide with sodium hydroxide, but with ammonia, they form a deep blue solution of tetraamminecopper(II) complex. Always refer to reliable sources or color charts for correct identification.

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