Question detail

Describe the test for identifying the presence of sulfate ions in an aqueous solution. Include the expected observation.

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Topic

Reactions of ions in aqueous solution (A-level only)

Question

Describe the test for identifying the presence of sulfate ions in an aqueous solution. Include the expected observation.

Answer

To test for sulfate ions, add a few drops of barium chloride solution to the aqueous solution. A white precipitate of barium sulfate will form if sulfate ions are present. This answer is anchored to Aqueous ion tests (A-level only).

Explanation

To test for sulfate ions, add a few drops of barium chloride solution to the aqueous solution. A white precipitate of barium sulfate will form if sulfate ions are present. is the best answer because it directly supports the AQA A-Level Chemistry objective to required practical: carry out test-tube reactions to identify cations and anions. This reasoning is anchored to Aqueous ion tests (A-level only) in Reactions of ions in aqueous solution (A-level only), and it separates required from similar A-Level ideas rather than relying on a vague recall statement. Other options are weaker if they use the wrong evidence, calculation, mechanism, observation, unit, or conclusion for this subtopic.

Common mistake

Identifying Cations with Sodium Hydroxide

Students often incorrectly assume that all metal ions will produce a precipitate when reacted with sodium hydroxide.

To correctly identify cations, remember that only certain metal ions form insoluble hydroxides. For example, when testing with sodium hydroxide, use the formula for the reaction: Metal Ion + NaOH → Metal Hydroxide (precipitate). For instance, Fe²⁺ + 2NaOH → Fe(OH)₂ (s) shows a green precipitate, while Na⁺ does not produce any precipitate. Always check the solubility rules for hydroxides.

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