Learning objective

Explain why ultraviolet light is needed for radical formation.

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Topic

Alkanes

Subtopic

Chlorination of alkanes

AQA A Level ChemistryOrganic chemistry

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Short explanation

The cause for the need for ultraviolet (UV) light in radical formation during the chlorination of alkanes is the energy required to break the Cl-Cl bond. This energy is provided by UV light, which initiates the process by promoting the dissociation of chlorine molecules into chlorine radicals. The mechanism involves the absorption of UV light, leading to the homolytic cleavage of the Cl-Cl bond, resulting in two reactive chlorine radicals. The effect of this radical formation is the initiation of a chain reaction that allows for the substitution of hydrogen atoms in alkanes. Consequently, this process enables the chlorination of alkanes, producing chlorinated hydrocarbons.

Key concepts

ultraviolet lightradical formation

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This objective helps connect Chlorination of alkanes to exam-style questions, flashcards, and revision notes for Alkanes.

Common mistakes

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  • Misunderstanding Ultraviolet Light's Role: Ultraviolet light causes the homolytic cleavage of chlorine molecules (Cl2) into two chlorine radicals (Cl•). This radical formation is essential because these chlorine radicals initiate the chain reaction of free-radical substitution, allowing the chlorination of alkanes to occur effectively.

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