Question detail

What is the main mechanism of nitration of benzene?

Try the question, check the answer, then read the explanation to understand the curriculum point.

At a glance

MCQ

Type

practice

Style

Topic

Aromatic chemistry (A-level only)

Question

  1. A. Electrophilic substitution
  2. B. Nucleophilic substitution
  3. C. Addition reaction
  4. D. Elimination reaction

Answer

Electrophilic substitution

Explanation

The nitration of benzene is an electrophilic substitution reaction where the electrophile (nitronium ion, NO2+) attacks the electron-rich benzene ring, substituting a hydrogen atom.

Common mistake

Nitration Reaction Misunderstanding

Students often confuse the nitration of benzene with a simple addition reaction, thinking that the nitro group is added directly to the benzene ring.

Remember that nitration is an electrophilic substitution reaction. The formula for the reaction is C6H6 + HNO3 → C6H5NO2 + H2O. Substitute the reactants into the equation to show that the benzene ring retains its structure while substituting a hydrogen atom for a nitro group.

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