Question detail
Which of the following reactions is an example of electrophilic substitution in benzene?
Try the question, check the answer, then read the explanation to understand the curriculum point.
At a glance
MCQ
Type
practice
Style
Topic
Aromatic chemistry (A-level only)
Question
- A. Hydrogenation
- B. Nitration
- C. Dehydrogenation
- D. Hydrolysis
Answer
Nitration
Explanation
Nitration is a classic example of electrophilic substitution where a nitro group is introduced into the benzene ring, demonstrating the mechanism of electrophilic substitution.
Common mistake
Incorrect intermediate: benzyl cation
Students think the electrophilic substitution proceeds via a benzyl carbocation intermediate that retains aromaticity.
The correct intermediate is a σ‑complex (arenium ion) where the aromatic π system is temporarily disrupted; aromaticity is restored after deprotonation.
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