Question detail
A compound has a carbon-13 NMR spectrum that shows a peak at 75 ppm. What does this indicate about the carbon environment in the compound?
Try the question, check the answer, then read the explanation to understand the curriculum point.
At a glance
Question
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exam_style
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Topic
Nuclear magnetic resonance spectroscopy (A-level only)
Question
A compound has a carbon-13 NMR spectrum that shows a peak at 75 ppm. What does this indicate about the carbon environment in the compound?
Answer
The peak at 75 ppm indicates that the carbon is likely in a carbon environment that is adjacent to electronegative atoms, such as oxygen or nitrogen, or is part of a carbonyl group. This suggests that the carbon is in a functional group that influences its chemical shift. This answer is anchored to NMR spectroscopy (A-level only).
Explanation
The peak at 75 ppm indicates that the carbon is likely in a carbon environment that is adjacent to electronegative atoms, such as oxygen or nitrogen, or is part of a carbonyl group. This suggests that the carbon is in a functional group that influences its chemical shift. is the best answer because it directly supports the AQA A-Level Chemistry objective to use NMR evidence with other analytical data to determine structures. This reasoning is anchored to NMR spectroscopy (A-level only) in Nuclear magnetic resonance spectroscopy (A-level only), and it separates NMR from similar A-Level ideas rather than relying on a vague recall statement. Other options are weaker if they use the wrong evidence, calculation, mechanism, observation, unit, or conclusion for this subtopic.
Common mistake
Misinterpreting NMR Peaks
Students often misinterpret the number of peaks in an NMR spectrum, thinking each peak represents a different carbon atom instead of different carbon environments.
Students should remember that each peak corresponds to a unique carbon environment, not just the number of carbon atoms present.
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