Question detail
Describe the procedure for measuring the enthalpy change of a reaction using a calorimeter.
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Topic
AS practical skills and required practical activities
Question
Describe the procedure for measuring the enthalpy change of a reaction using a calorimeter.
Answer
To measure the enthalpy change, first, prepare a calorimeter by adding a known volume of water and measuring its initial temperature. Then, add the reactants to the calorimeter and stir. Record the highest or lowest temperature reached after the reaction has occurred. The enthalpy change can be calculated using the formula ΔH = - (m × c × ΔT) / n, where m is the mass of water, c is the specific heat capacity of water, ΔT is the change in temperature, and n is the number of moles of the limiting reactant. This answer is anchored to AS required practical activities.
Explanation
To measure the enthalpy change, first, prepare a calorimeter by adding a known volume of water and measuring its initial temperature. Then, add the reactants to the calorimeter and stir. Record the highest or lowest temperature reached after the reaction has occurred. The enthalpy change can be calculated using the formula ΔH = - (m × c × ΔT) / n, where m is the mass of water, c is the specific heat capacity of water, ΔT is the change in temperature, and n is the number of moles of the limiting reactant. is the best answer because it directly supports the AQA A-Level Chemistry objective to required practical 2: measure an enthalpy change. This reasoning is anchored to AS required practical activities in AS practical skills and required practical activities, and it separates required practical from similar A-Level ideas rather than relying on a vague recall statement. Other options are weaker if they use the wrong evidence, calculation, mechanism, observation, unit, or conclusion for this subtopic.
Common mistake
Incorrect Measurement of Enthalpy Change
Students often forget to account for the specific heat capacity of the solution when calculating the enthalpy change, leading to inaccurate results.
To fix this, remember to use the formula q = mcΔT, where q is the heat energy, m is the mass of the solution, c is the specific heat capacity, and ΔT is the change in temperature. Substitute the values correctly and ensure to include units in your final answer. For example, if you have 100 g of water (m = 100 g), with a specific heat capacity of 4.18 J/g°C (c), and a temperature change of 10°C (ΔT), the calculation would be: q = 100 g × 4.18 J/g°C × 10°C = 4180 J. Thus, the enthalpy change is 4180 J.
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