Learning objective

Predict that oxygen is produced at the anode unless the solution contains halide ions.

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5

Flashcards

7

Questions

Topic

Electrolysis

Subtopic

Electrolysis of aqueous solutions

AQA GCSE ChemistryChemical changes

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Understand this objective

Short explanation

During the electrolysis of aqueous solutions, oxygen is typically produced at the anode. This occurs because water molecules can dissociate into hydroxide ions (OH⁻) and hydrogen ions (H⁺), and the oxidation of these hydroxide ions leads to the formation of oxygen gas. However, if halide ions such as chloride (Cl⁻), bromide (Br⁻), or iodide (I⁻) are present in the solution, they will be preferentially oxidized at the anode, resulting in the production of chlorine, bromine, or iodine instead of oxygen. Thus, the presence of halide ions alters the expected product at the anode during electrolysis.

Key concepts

anodeoxygen

Why it matters

This objective helps connect Electrolysis of aqueous solutions to exam-style questions, flashcards, and revision notes for Electrolysis.

Common mistakes

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  • Misunderstanding Anode Products: Students should remember that oxygen is produced at the anode unless halide ions are present, in which case chlorine, bromine, or iodine will be produced instead.

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