Question detail

In the electrolysis of molten NaCl, which half‑equation would you write for the cathode and which for the anode? State the products formed at each electrode.

Try the question, check the answer, then read the explanation to understand the curriculum point.

At a glance

Question

Type

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Style

Topic

Electrolysis

Question

In the electrolysis of molten NaCl, which half‑equation would you write for the cathode and which for the anode? State the products formed at each electrode.

Answer

Cathode: Na⁺ + e⁻ → Na (solid). The product is metallic sodium. Anode: 2Cl⁻ → Cl₂(g) + 2e⁻. The product is chlorine gas. The cathode half‑equation shows reduction (gain of electrons) and the anode half‑equation shows oxidation (loss of electrons).

Explanation

This question requires the student to apply the distinction between cathode and anode half‑equations to a specific example, testing application and recall of the reactivity series. It also checks knowledge of the products of molten NaCl electrolysis.

Common mistake

Confusing Cathode and Anode Half Equations

Students often confuse the half equations for the cathode and anode during electrolysis, mistakenly attributing the reduction process to the anode instead of the cathode.

Remember that reduction occurs at the cathode where positive ions gain electrons, while oxidation occurs at the anode where negative ions lose electrons. Practice identifying the charge of ions to help distinguish between the two.

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