Which of the following is the first member of the alcohol homologous series?

The correct option is Methanol.

The correct option is Methanol. Methanol is correct because it directly supports the approved learning objective to describe alcohols as compounds that contain the functional group –OH. This belongs to Alcohols within Reactions of alkenes and alcohols (chemistry only), so the answer must use the correct organic chemistry context. The other options are incorrect when they confuse the organic family, formula type, reaction condition, product, or property being tested. Keep molecular formula, structural formula, displayed formula, and general formula distinct. Do not confuse alkanes with alkenes, saturated with unsaturated, cracking with combustion, polymers with monomers, or hydrocarbons with oxygen-containing alcohols and carboxylic acids. When formulae are used, preserve the stored notation exactly and explain the GCSE chemistry idea in words rather than using unsupported displayed-formula diagrams.