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Transition metals (A-level only)

This A-level-only topic develops d-block chemistry through complex ions and variable oxidation states.

13

Objectives

10

Flashcards

10

Questions

90 min

Study time

AqaA LevelChemistryInorganic chemistry

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What you need to know

13 objective pages available

Transition-metal characteristics (A-level only)4 objectives
  • Define a transition metal as a d-block element forming at least one ion with an incomplete d subshell.
  • Explain variable oxidation states in transition metals.
  • Explain why transition-metal ions are often coloured.
  • Explain catalytic activity of transition metals and their compounds.
Complex ions and ligand substitution (A-level only)5 objectives
  • Define ligand and coordinate bond.
  • Explain coordination number in complex ions.
  • Describe octahedral, tetrahedral and square planar complexes.
  • Explain ligand substitution reactions.
  • Use equations to represent ligand substitution.
Isomerism and redox in transition-metal chemistry (A-level only)4 objectives
  • Identify cis-trans and optical isomerism in complex ions.
  • Explain redox changes involving transition-metal ions.
  • Use transition-metal redox titration data in calculations.
  • Interpret colour changes in transition-metal reactions.

Key terms

LigandCoordination numberOxidation stated-d transitionCatalystCoordinate bondCoordination NumberCoordination complexComplex ionLigand substitutionTetrahedral complex

Exam tips

  • Use clear and precise language in definitions: When defining transition metals, ensure you mention the incomplete d subshell to avoid ambiguity.
  • Show your working in calculations: Always show your calculations step-by-step, including the formula used and the final answer with units.

Common mistakes

  • Confusing transition metals with main group elements: Remember that transition metals are defined by their ability to form ions with incomplete d subshells, while main group elements do not have this characteristic.
  • Confusing oxidation states with charges: Remember that oxidation states refer to individual elements, while the charge refers to the entire compound.

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