Question detail

Describe a test to identify the presence of alcohols in a sample. Include the expected observation.

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At a glance

Question

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Topic

Alcohols

Question

Describe a test to identify the presence of alcohols in a sample. Include the expected observation.

Answer

To test for alcohols, add a few drops of acidified potassium dichromate to the sample and warm it gently. If an alcohol is present, the orange solution will turn green due to the reduction of dichromate ions.

Explanation

This question tests the student's understanding of qualitative analysis for alcohols. The answer demonstrates knowledge of the specific reagents and the expected color change, which indicates the presence of an alcohol functional group.

Common mistake

Testing for Alcohols

Students often confuse the test for alcohols with the test for aldehydes, leading to incorrect conclusions about the presence of functional groups.

To correctly test for alcohols, use the appropriate reagent, such as sodium dichromate in dilute sulfuric acid, which will oxidize primary and secondary alcohols, changing color from orange to green. Ensure to write the balanced equation for the reaction: C2H5OH + [O] → CH3COOH + H2O. This shows the oxidation of ethanol to acetic acid.

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