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Carboxylic acids and derivatives (A-level only)

This A-level-only topic links acidity, nucleophilic addition-elimination and derivatives.

4

Objectives

10

Flashcards

10

Questions

88 min

Study time

AqaA LevelChemistryOrganic chemistry

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What you need to know

4 objective pages available

Carboxylic acids, esters and acyl derivatives (A-level only)4 objectives
  • Explain acidic behaviour of carboxylic acids.
  • Describe esterification and hydrolysis reactions.
  • Explain reactions of acyl chlorides and acid anhydrides.
  • Outline nucleophilic addition-elimination mechanisms for acyl derivatives.

Key terms

Carboxylic acidDissociation constant (Kₐ)EsterificationHydrolysisAcyl chlorideNucleophile

Exam tips

  • Use equilibrium expressions correctly: When dealing with acid-base equilibria, always write the correct equilibrium expression for Kₐ.
  • Balance chemical equations: Always ensure that your chemical equations are balanced in terms of both atoms and charge.

Common mistakes

  • Confusing carboxylic acids with alcohols: Remember that carboxylic acids can donate a proton due to the presence of the carboxyl group, while alcohols cannot.
  • Confusing esterification with hydrolysis: Remember that esterification forms an ester and water, while hydrolysis breaks down an ester into a carboxylic acid and an alcohol.

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