Learning objective

Describe London dispersion forces between molecules.

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5

Flashcards

7

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Topic

Bonding

Subtopic

Intermolecular forces

AQA A Level ChemistryPhysical chemistry

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Short explanation

London dispersion forces are weak intermolecular forces that arise from temporary fluctuations in electron distribution within molecules. These fluctuations create instantaneous dipoles, which induce dipoles in neighboring molecules, resulting in an attractive force. The strength of London dispersion forces increases with the size of the molecules and their surface area, as larger molecules have more electrons, leading to greater polarizability. Consequently, substances with significant London dispersion forces may exhibit higher boiling points due to the increased energy required to overcome these forces during a phase change.

Key concepts

London dispersion forcesmolecular size

Why it matters

This objective helps connect Intermolecular forces to exam-style questions, flashcards, and revision notes for Bonding.

Common mistakes

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  • Misunderstanding London Dispersion Forces: London dispersion forces are weak intermolecular forces that arise from temporary dipoles in molecules. To clarify, remember that these forces increase with molecular size and surface area. For example, larger molecules have more electrons, leading to stronger temporary dipoles and thus stronger London dispersion forces. Always compare them to other forces to understand their relative weakness.

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Describe London dispersion forces between molecules. | Bonding |… | ExamCompanion