Question detail

What happens to the position of equilibrium when the pressure is increased in a reaction involving gaseous reactants and products?

Try the question, check the answer, then read the explanation to understand the curriculum point.

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Topic

Chemical equilibria, Le Chatelier's principle and Kc

Question

What happens to the position of equilibrium when the pressure is increased in a reaction involving gaseous reactants and products?

Answer

According to Le Chatelier's principle, increasing the pressure will shift the equilibrium position towards the side with fewer moles of gas. This occurs because the system attempts to counteract the change by reducing the pressure, leading to a higher concentration of the products if they are on the side with fewer gas moles. This answer is anchored to Equilibrium and Le Chatelier's principle.

Explanation

According to Le Chatelier's principle, increasing the pressure will shift the equilibrium position towards the side with fewer moles of gas. This occurs because the system attempts to counteract the change by reducing the pressure, leading to a higher concentration of the products if they are on the side with fewer gas moles. is the best answer because it directly supports the AQA A-Level Chemistry objective to use Le Chatelier's principle to predict the effect of pressure changes. This reasoning is anchored to Equilibrium and Le Chatelier's principle in Chemical equilibria, Le Chatelier's principle and Kc, and it separates Le Chatelier from similar A-Level ideas rather than relying on a vague recall statement. Other options are weaker if they use the wrong evidence, calculation, mechanism, observation, unit, or conclusion for this subtopic.

Common mistake

Pressure Change Misunderstanding

Students often think that increasing pressure will always shift the equilibrium to the right, regardless of the reaction.

To fix this, remember that increasing pressure shifts the equilibrium towards the side with fewer moles of gas. Always analyze the balanced equation to determine the effect of pressure changes.

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