Question detail

Describe the procedure to measure the EMF of an electrochemical cell using a standard hydrogen electrode.

Try the question, check the answer, then read the explanation to understand the curriculum point.

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Topic

Electrode potentials and electrochemical cells (A-level only)

Question

Describe the procedure to measure the EMF of an electrochemical cell using a standard hydrogen electrode.

Answer

To measure the EMF of an electrochemical cell, connect the cell to a voltmeter. Ensure the standard hydrogen electrode is at 1 atm pressure and 298 K. Record the voltage reading, which represents the EMF of the cell. This answer is anchored to Standard electrode potentials (A-level only).

Explanation

To measure the EMF of an electrochemical cell, connect the cell to a voltmeter. Ensure the standard hydrogen electrode is at 1 atm pressure and 298 K. Record the voltage reading, which represents the EMF of the cell. is the best answer because it directly supports the AQA A-Level Chemistry objective to required practical: measure the EMF of an electrochemical cell. This reasoning is anchored to Standard electrode potentials (A-level only) in Electrode potentials and electrochemical cells (A-level only), and it separates electrochemical cell from similar A-Level ideas rather than relying on a vague recall statement. Other options are weaker if they use the wrong evidence, calculation, mechanism, observation, unit, or conclusion for this subtopic.

Common mistake

Measuring EMF of Electrochemical Cells

Students often forget to account for the correct polarity when measuring the EMF of an electrochemical cell, leading to incorrect potential values.

To fix this, remember to connect the positive terminal of the voltmeter to the more positive electrode and the negative terminal to the more negative electrode. Use the formula for EMF: EMF = E(cathode) - E(anode). Substitute the standard electrode potentials for the cathode and anode, calculate the difference, and ensure the final answer is expressed in volts (V). Keep the correction anchored to Standard electrode potentials (A-level only) and the objective: Required practical: measure the EMF of an electrochemical cell.

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