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Acids and bases (A-level only)

This A-level-only topic develops quantitative and qualitative acid-base chemistry.

20

Objectives

100

Flashcards

94

Questions

90 min

Study time

AQAA LevelChemistryPhysical chemistry

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Syllabus checklist

What you need to know

20 objective pages available

Brønsted-Lowry acids and bases (A-level only)4 objectives
  • Define Brønsted-Lowry acids and bases.
  • Identify conjugate acid-base pairs.
  • Write equations showing proton transfer.
  • Distinguish acid strength from concentration.
pH and Kw (A-level only)4 objectives
  • Calculate pH from hydrogen ion concentration.
  • Calculate hydrogen ion concentration from pH.
  • Use Kw to calculate hydrogen ion or hydroxide ion concentrations.
  • Apply pH calculations to strong acids and strong bases.
Weak acids, Ka and pKa (A-level only)4 objectives
  • Construct Ka expressions for weak acids.
  • Calculate pH of a weak acid from concentration and Ka.
  • Convert between Ka and pKa.
  • Explain weak-acid behaviour in terms of partial dissociation.
pH curves, titrations and indicators (A-level only)4 objectives
  • Perform calculations using acid-base titration data.
  • Sketch and explain pH curves for combinations of weak and strong monoprotic acids and bases.
  • Select suitable indicators using pH curves and transition ranges.
  • Required practical: investigate pH changes in weak acid and strong base or strong acid and weak base titrations.
Buffer action (A-level only)4 objectives
  • Explain qualitatively how acidic buffers resist pH change.
  • Explain qualitatively how basic buffers resist pH change.
  • Calculate the pH of acidic buffer solutions.
  • Explain applications of buffer solutions.

Key terms

Brønsted-Lowry acidBrønsted-Lowry baseAcid StrengthAcid ConcentrationpHhydrogen ion concentrationKwhydroxide ion concentrationstrong acidKa expressionweak acidKa

Exam tips

  • Understanding Brønsted-Lowry Acids and Bases: Explain clearly by define Brønsted-Lowry acids as proton donors and bases as proton acceptors. Link the point to Brønsted-Lowry acids and bases (A-level only), then state the evidence, calculation, mechanism, observation, or conclusion required by the question.
  • Identifying Conjugate Acid-Base Pairs: When identifying conjugate acid-base pairs, remember that a conjugate acid is formed when a base gains a proton, and a conjugate base is formed when an acid loses a proton.

Common mistakes

  • Misunderstanding Brønsted-Lowry Definitions: Remember that Brønsted-Lowry acids are defined as proton donors and bases as proton acceptors. For example, in the reaction HCl + H2O → Cl- + H3O+, HCl donates a proton to water, making it a Brønsted-Lowry acid.
  • Identifying Conjugate Pairs: To correctly identify conjugate acid-base pairs, remember that a conjugate acid is formed when a base gains a proton (H⁺), and a conjugate base is formed when an acid loses a proton. For example, in the reaction HCl + H₂O ⇌ Cl⁻ + H₃O⁺, HCl is the acid and Cl⁻ is its conjugate base, while H₂O is the base and H₃O⁺ is its conjugate acid.

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Acids and bases (A-level only) Revision - AQA Chemistry 7405 | ExamCompanion