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Learning objective

Explain how first and successive ionisation energies provide evidence for shells and subshells.

Read the explanation, check the common trap, then practise with flashcards and questions.

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Topic

Atomic structure

Subtopic

Electron configuration and ionisation energy

Aqa A Level ChemistryPhysical chemistry

Study support

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Quick explanation

Explain how first and successive ionisation energies provide evidence for shells and subshells

  • This point belongs to Atomic structure, especially Electron configuration and ionisation energy.
  • You need to be able to explain how first and successive ionisation energies provide evidence for shells and subshells.
  • The key ideas to know are subshell and shell.
  • Use the linked flashcards and practice questions to check recall, then practise applying the idea in an exam-style answer.

Key concepts

subshellshell

Why it matters

This objective helps connect Electron configuration and ionisation energy to exam-style questions, flashcards, and revision notes for Atomic structure.

Quick student answer

Which of the following best explains why the second ionisation energy of sodium (Na) is much higher than its first ionisation energy?

Direct answer

c

Key terms

  • Ionisation energy: The energy required to remove one mole of electrons from one mole of gaseous atoms or ions.
  • Subshell: A group of orbitals within a shell that share the same angular momentum quantum number l and have a characteristic energy.

Common trap

Confusing ionisation energy with ionisation potential: Clarify that ionisation energy (kJ mol⁻¹) is the molar quantity, while ionisation potential (eV) is the energy per electron. Both describe the same process but are expressed in different units.

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