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Atomic structure key terms

Study Atomic structure with curriculum-aligned Key Terms resources, practice links, and exam-focused support.

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Atomic structure

AqaA LevelChemistryPhysical chemistry

Key terms

  • Plum‑pudding model

    An early atomic model suggesting a positively charged sphere with embedded electrons.

  • Gold‑foil experiment

    Rutherford’s experiment using α‑particles to probe atomic structure, revealing a small, dense nucleus.

  • Proton

    A positively charged baryon found in the nucleus, with a relative mass of ≈1.007 amu.

  • Neutron

    A neutral baryon in the nucleus, with a relative mass of ≈1.009 amu.

  • Nucleus

    The central part of an atom containing protons and neutrons.

  • Atomic number

    The number of protons in the nucleus, which determines the element.

  • Isotope

    Atoms of the same element with identical proton numbers but differing neutron numbers.

  • Ion

    An atom or molecule that carries a net electric charge due to loss or gain of electrons.

  • Mass number

    The sum of protons and neutrons in an atom’s nucleus, expressed as a whole number.

  • Isotope

    Atoms of the same element that have the same number of protons but different numbers of neutrons, giving different mass numbers.

  • Isotope

    An atom of a given element that has the same number of protons but a different number of neutrons, resulting in a different mass number.

  • Mass number

    The total number of protons and neutrons in an atomic nucleus, expressed as A = Z + N.

  • Time‑of‑flight (TOF)

    The duration an ion takes to travel from the acceleration region to the detector in a mass spectrometer.

  • Mass‑to‑charge ratio (m/z)

    The ratio of an ion’s mass to its charge, a fundamental parameter used to identify ions in mass spectrometry.

  • Relative Atomic Mass

    The weighted average mass of an atom of an element compared to 1/12th of the mass of a carbon-12 atom.

  • Mass Spectrum

    A graphical representation of the mass-to-charge ratios of ions, showing the abundance of each ion.

  • Isotopic Abundance

    The relative proportion of a particular isotope in a naturally occurring sample, expressed as a percentage.

  • Relative Atomic Mass

    The weighted average mass of an element’s isotopes, calculated from their masses and natural abundances.

  • Mass number

    The total number of protons and neutrons in an atom’s nucleus.

  • Atomic mass

    The weighted average mass of all naturally occurring isotopes of an element, expressed in atomic mass units (u).

  • Subshell

    A set of orbitals with the same principal quantum number n and azimuthal quantum number l (s, p, d, f).

  • Electron configuration

    A notation that shows the distribution of electrons among the atomic orbitals of an atom or ion.

  • Ionisation Energy

    The energy required to remove an electron from an atom in the gaseous state.

  • Nuclear Charge

    The total charge of the nucleus, determined by the number of protons.

  • Ionisation energy

    Energy required to remove one electron from a gaseous atom or ion.

  • Successive ionisation energy

    Energy required to remove each successive electron from an atom or ion.

  • Ionisation energy

    The energy required to remove one mole of electrons from one mole of gaseous atoms or ions.

  • Subshell

    A group of orbitals within a shell that share the same angular momentum quantum number l and have a characteristic energy.

  • Ionisation Energy

    The energy required to remove one mole of electrons from one mole of gaseous atoms.

  • Atomic Radius

    The distance from the nucleus of an atom to the outermost shell of electrons.

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