Definition and Physical Meaning of Electromotive Force
Electromotive force, abbreviated as e.m.f., is defined as the total electrical work done by a source in moving a unit positive charge completely around a circuit. It represents the energy supplied by the source to each coulomb of charge as it passes through the source.
Physically, e.m.f. is the cause of current flow in a circuit. It is the energy per unit charge provided by the source to overcome the internal resistance of the source and any other components in the circuit.
The unit of e.m.f. is the volt (V), where 1 volt equals 1 joule per coulomb (1 V = 1 J/C).
- e.m.f. = work done by source / charge moved
- Unit: volt (V) = joule per coulomb (J/C)
- Represents energy supplied per unit charge
Formula and Calculation of Electromotive Force
The relationship between work done (W), charge (Q), and electromotive force (E) is given by the formula:
\[ E = \frac{W}{Q} \] where: E is the e.m.f. in volts (V), W is the work done in joules (J), and Q is the charge in coulombs (C).
This formula can be rearranged to find work done or charge if the other quantities are known: \[ W = E \times Q \quad \text{or} \quad Q = \frac{W}{E} \]
- E = W/Q where E in volts, W in joules, Q in coulombs
- Rearrangements: W = E × Q, Q = W / E
- Example: If a source does 12 J of work to move 4 C, e.m.f. = 12 J / 4 C = 3 V
Distinction Between Electromotive Force and Potential Difference
Electromotive force is the energy supplied per unit charge by the source when moving charge around the entire circuit, including overcoming internal resistance.
Potential difference (p.d.) is the energy used per unit charge when charge passes through a particular component or resistor in the circuit.
While both e.m.f. and p.d. are measured in volts and represent energy per unit charge, e.m.f. refers to the source's energy supply, and p.d. refers to energy used by components.
- e.m.f.: energy supplied per unit charge by source
- p.d.: energy used per unit charge by component
- Both measured in volts (V) but represent different energy transfers
Circuit Representation and Practical Considerations
In circuit diagrams, a source of e.m.f. such as a battery or cell is represented by a pair of lines: the longer line is the positive terminal and the shorter line the negative terminal.
The e.m.f. of a source is the maximum potential difference it can provide when no current flows (open circuit).
When current flows, some energy is lost overcoming the internal resistance of the source, so the terminal p.d. is less than the e.m.f.
- Battery symbol: long line (+), short line (-)
- e.m.f. is maximum voltage with no current (open circuit)
- Terminal p.d. < e.m.f. when current flows due to internal resistance
Worked Example: Calculating Electromotive Force
A battery does 24 joules of work to move 8 coulombs of charge around a circuit. Calculate the e.m.f. of the battery.
Using the formula: \[ E = \frac{W}{Q} = \frac{24\,\text{J}}{8\,\text{C}} = 3\,\text{V} \]
Therefore, the e.m.f. of the battery is 3 volts. This means the battery supplies 3 joules of energy to each coulomb of charge passing through it.
- Given: W = 24 J, Q = 8 C
- Calculate: E = W / Q = 24 J / 8 C = 3 V
- Answer: e.m.f. = 3 volts
At-a-glance summary
Comparison table
| Step | Physics Detail | Evidence | Exam Use |
|---|---|---|---|
| Definition | e.m.f. is work done per unit charge by source | Formula E = W/Q, units volts (V) | Define and explain e.m.f. in exam questions |
| Physical Meaning | Energy supplied to move charge around circuit | Energy per coulomb, overcomes internal resistance | Explain how e.m.f. drives current |
| Formula Application | Calculate e.m.f. from work and charge | Substitute values into E = W/Q | Solve numerical problems involving e.m.f. |
| Distinction | e.m.f. vs potential difference | e.m.f. energy supplied; p.d. energy used | Answer conceptual questions distinguishing terms |
| Circuit Symbols | Battery symbol shows source of e.m.f. | Long line positive, short line negative | Draw and interpret circuit diagrams |
Active recall
Quick check
1. What is the unit of electromotive force?
Volt (V), which is joule per coulomb (J/C).
2. If a source does 15 J of work to move 5 C of charge, what is its e.m.f.?
E = W/Q = 15 J / 5 C = 3 V.
3. How does e.m.f. differ from potential difference?
e.m.f. is energy supplied per unit charge by the source around the full circuit; potential difference is energy used per unit charge across a component.
4. Why is the terminal potential difference usually less than the e.m.f. when current flows?
Because some energy is lost overcoming the internal resistance of the source, reducing the voltage available at the terminals.
