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Learning objective

Explain the procedures for testing and identifying the following anions: (a) carbonate (CO₃²⁻) through its reaction with dilute acid and subsequent carbon dioxide gas detection; (b) halides (chloride Cl⁻, bromide Br⁻, iodide I⁻) by acidifying with dilute nitric acid followed by the addition of aqueous silver nitrate; (c) nitrate (NO₃⁻) by reduction with aluminum foil and sodium hydroxide, then testing for ammonia gas; (d) sulfate (SO₄²⁻) by acidifying with dilute nitric acid and adding barium nitrate; (e) sulfite (SO₃²⁻) through reaction with acidified potassium manganate(VII).

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Cambridge IGCSE ChemistryExperimental techniques and chemical analysisCore content

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Explain the procedures for testing and identifying the following anions: (a) carbonate (CO₃²⁻) through its reaction with dilute acid and subsequent carbon dioxide gas detection; (b) halides (chloride Cl⁻, bromide Br⁻, iodide I⁻) by acidifying with dilute nitric acid followed by the addition of aqueous silver nitrate; (c) nitrate (NO₃⁻) by reduction with aluminum foil and sodium hydroxide, then testing for ammonia gas; (d) sulfate (SO₄²⁻) by acidifying with dilute nitric acid and adding barium nitrate; (e) sulfite (SO₃²⁻) through reaction with acidified potassium manganate(VII)

  • This point belongs to Identification of ions and gases, especially Identification of ions and gases outcomes.
  • You need to be able to explain the procedures for testing and identifying the following anions: (a) carbonate (CO₃²⁻) through its reaction with dilute acid and subsequent carbon dioxide gas detection; (b) halides (chloride Cl⁻, bromide Br⁻, iodide I⁻) by acidifying with dilute nitric acid followed by the addition of aqueous silver nitrate; (c) nitrate (NO₃⁻) by reduction with aluminum foil and sodium hydroxide, then testing for ammonia gas; (d) sulfate (SO₄²⁻) by acidifying with dilute nitric acid and adding barium nitrate; (e) sulfite (SO₃²⁻) through reaction with acidified potassium manganate(VII).
  • The key ideas to know are Describe, Identify, and Explain.
  • Use the linked flashcards and practice questions to check recall, then practise applying the idea in an exam-style answer.

Key concepts

DescribeIdentifyExplain

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Paper 3 structured question: Identification of ions and gases

Paper 3Theory (Core)1 marks

Description

Anion Tests

Describe the procedure for testing for carbonate ions, halides, and sulfate ions.

  1. a

    State the test for carbonate ions (CO₃²⁻).

    Aim for approximately 1 distinct marking point.

    [1]
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